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B.Sc. General Chemistry notes:
B.Sc. General Chemistry notes:
- Atomic structure - Aufban principle, Hund’s rule and electronic configurations of elements – stability of half filled and completely filled, orbital — shapes of S, P, d and f orbitals. S, P, d and f blok elements – classification and characteristic properties – DOWNLOAD
- Periodicity of Properties – Definition and periodicity of the following properties – atomic radii, ionic radii. ionisation potential, electron affinity and electronegativity (no determination) and diagonal relationship with examples – (a) DOWNLOAD (b) DOWNLOAD (c)DOWNLOAD (d) DOWNLOAD
- Bonding in chemistry – Bonds and molecules, Observable properties of chemical bonds, Why do chemical bonds form?, The shared-electron model of chemical bonding, Polar and nonpolar bonds, The Shapes of Molecules: the VSEPR model, Hybrid orbitals: the valence bond model, The molecular orbital Model, Bonding in coordination complexes, Bonding in metals and semiconductors-DOWNLOAD
- Principles of inorganic Analysis – Principles of acid base equilibria, commonion effect and solubitity product and their applications in qualitative analysis. Reactions involved in the separation and identification of cations and anions in the analysis – (a) DOWNLOAD (b) DOWNLOAD (c) DOWNLOAD (d) DOWNLOAD(e) DOWNLOAD (f) DOWNLOAD
- Nomenclature of organic compounds - IUPAC recommendations for naming simple aliphatic, alicyclic and aromatic compounds – (a) DOWNLOAD (b) DOWNLOAD
- Free radical reactions - Mechanism of free radical substitution in alkanes, Halogenation of Alkanes, Chlorination versus Bromination, Stereochemistry of Halogenation, Radical Halogenation at an Allylic Carbon, Radical Additions to Double Bonds, free radical polymerization – DOWNLOAD
- Alkenes – General methods of preparation properties of alkenes – electrophilic and free radical addition – addition reactions with hydrogen, halogens, hydrogen halide (mark ownikoffs rule) hydrogen bromide (peroxide effect) sulphuric acid, water, hydroboration, ozonolysis, hydroxylation with KMnO4 – (a) DOWNLOAD (b)DOWNLOAD (c) DOWNLOAD
- Quantum Chemistry - Planck’s theory – photo electric effect – compton effect – de Broglie’s relationship Heisenberg’s uncertaimty principle – Schrodinger wave equation (no derivation) – significance of wave functions – probability distribution of electrons – radial probability distribution curves – (a) DOWNLOAD (b) DOWNLOAD (c)DOWNLOAD
- Gaseous State – Gas Laws from the kinetic theory of gases. Transport properties – viscosity – thermal conductivity – diffusion – Maxwell’s distribution of molecular velocities (no derivation) – mean – rms, most probable, velocity equi partition of energy – heat capacity - (a) DOWNLOAD (b) DOWNLOAD (c) DOWNLOAD (d) DOWNLOAD(e) DOWNLOAD
- Types of Chemical Bonds - Lewis Dot Structures for Elements, Formation of Ionic Solids, Born-Haber Cycle for the Formation of NaCl, Lattice Energy, Properties of Ionic Compounds, Electronegativity and Bond Polarity, Resonance Structures, Bond Energies, Bond Lengths – DOWNLOAD (b) DOWNLOAD (c)DOWNLOAD (d) DOWNLOAD
- Ionic Bonds - Formation of Cations & Anions, Ionic Bond Formation, Polyatomic ions, Properties of Ionic Compounds, Born-Haber Cycle, Born-Haber Cycle for NaCl – (a) DOWNLOAD (b)DOWNLOAD (c)DOWNLOAD (d) DOWNLOAD
- Valence-Shell Electron-Pair Repulsion (VSEPR) model, Molecular orbital(MO) theory, Valance bond(VB) theory - The Basic VSEPR Shapes, Summary of VSEPR Shapes, Molecular Shape and Polarity,
using VSEPR to predit shape, VB theory, Hybrid Orbitals, Molecular Orbital Theory, H2 Molecule, MO Theory and Other Diatomic Molecules, Combining VB and MO Theory, VSEPRgeometries – (a) DOWNLOAD (b) DOWNLOAD (c) DOWNLOAD (d)DOWNLOAD (e) DOWNLOAD (f) DOWNLOAD (g) DOWNLOAD
More notes to help you out:
Ap Chemistry Notes – Solubility Rules, Poly Atomic Naming, Common Units, Constants and Charges, Atomic Theory, Naming, Blackbody Radiation, Bohr Model, Wavelength, Quantum Values, Periodicity, Nuclear Chemistry, Ionization and Affinity, Reactions of Metals, Chemical Bonds, Lewis Structures, Lattice Energies of Ionic Solids, Electronegativity, Bond Lengths of Covalent Bonds, Electronegativity, VSEPR, Functional Groups, Complex Ions, Acidic and Basic Redox, Thermodynamics, Chemical Kineticsand Rate Laws, Equilibrium, Gas Laws, Acids and Bases, Equilibrium of Saturated, Soluable Salts, Kinetic Molecular Theory, Electro Chemistry, Balancing Redox Reactions – DOWNLOAD
Random Notes:
- Intermolecular force – Vanderwaals force, London dispersion force, dipole-dipole, hydrogen bonding, solubility.
- Mass relationship – atomic mass calculation, mole concept, stoichimetry co-efficient, percentage yield.
- Nuclear chemistry – Radioactivity, half-life calc., nuclear eqn, fission and fusion, mass energy relationship.
- Reaction in aqueous soln – precipitation rxn, solubility rule with ex., acid-base rxn., neutralization rxn., balancing redox rxn with examples, molarity.
- Solid, liquid, gases – Kinetic molecular theory, unit of pressure, gas law, effusion, diffusion, real gas, ideal behaviour, phase change, phase diagram with expl., cubic unit cell, x-ray diffraction, Mo theory, liquid crystal, semiconductor.
- Solution and colloids – Intermolecular force, energy change in soln., type of soln., Henry Law, Concentration terms, Raoult’s law, Colligative property, Vant Hoff’s factor, Osmosis, Colloids.
- (a) Equilibrium – Basic of equilibrium reaction, diagrammatic representations, Calculation with examples. (b) Chemical kinetics and equilibrium-1 – Rate of rxn. with graphical explanation, factors affecting, collision theory, maxwell – Boltzmann constant, Arrhenius theory, rate law. (c) Chemical kinetics and equilibrium-2 – Equilibrium constant, relationship Kp and Kc, Value of K, Le chatlie principle, Haber – Bosch process.
- Basic Chemistry – stuff like Avagadro number, mole, molarity, molality, atomic mass, molecular weight calculation, limiting reagents.
- Fermi hole and heaps
- Periodic table of elements
- Balancing nuclear reactions
- Carbonic acid equilibria
- Atomic structure
- Half life examples
- Molecular orbital
- limiting reagent calc.
- Nuclear energetics
- Short notes in basic chemistry – almost all topics covered in basicgeneral chemistry.